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Gas laws

AP Chemistry Zumdahl 7E Chapter 5 Notes

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AP Chemistry A. Allan Chapter 5 - Gases 5.1 Pressure A. Properties of gases 1. Gases uniformly fill any container 2. Gases are easily compressed 3. Gases mix completely with any other gas 4. Gases exert pressure on their surroundings a. Pressure = force/area B. Measuring barometric pressure 1. The barometer a. Inventor - Evangelista Torricelli (1643) 2. Units a. mm Hg (torr) (1) 760 torr = Standard pressure b. newtons/meter2 = pascal (Pa) (1) 101,325 Pa = Standard pressure c. atmospheres (1) 1 atmosphere = Standard pressure 5.2 The Gas Laws of Boyle, Charles, and Avogadro A. Boyle's Law (Robert Boyle, 1627 - 1691) 1. the product of pressure times volume is a constant, provided the temperature remains the same kPV = a. P is inversely related to V

Principles of Chemistry Chapter 5

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Chapter 5: Gases Section 5.2: Pressure Sunday, October 19, 2014 12:43 PM Pressure = Force / Area ? **note: atmospheric pressure is caused by the weight of air molecules as they are attracted by gravity (hence why pressure decreases as altitude decreases) ? Measuring Pressure ? Barometer - device that measures atmospheric pressure Long tube filled with mercury, essentially you pour the mercury out of the tube until it stops because the mercury creates a seal and a vacuum in the closed end of the tube -pressure decreases cause the mercury seal to fall lower -pressure increases cause the mercury seal to fall higher ? Units of Pressure ? Pascal - (Pa) unit for pressure, equal to one Newton / meter squared --> Force / area

Gas Stoich Notes

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preAP Chemistry 2013-2014 1 Name ___________________________ Period ______ I. Avogadro?s Law ? Avogadro?s Law states that ____________ volumes of gases at the __________ temperature and pressure contain equal numbers of particles. - At STP, _________________ particles (1 mol) will have a volume of ___________ Using Avogadro?s Law EX 1: Determine the volume (in L) occupied by 212 g of oxygen at STP. EX 2: Determine the density of nitrogen at STP. II. Ideal Gas Law ? Up to now we have always kept the ______________ of gas constant. Recognize that as the amount of gas changes, its corresponding _________________ changes. (Avogadro?s Law)

Chapter 11

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Kinetic Theory Of Gases Postulates of the Kinetic Theory of Gases: A gas consists of a large number of tiny particles that are in constant, random motion The gas particles occupy a net volume so small in relation to the volume of their container that their contribution to the total volume can be ignored The collisions between particles and the walls of the container are perfectly elastic (no energy transfer) Kinetic Theory of Gases relates temperature to average kinetic energy Kinetic Theory of Gases (aka Kinetic Molecular Theory) can be used to explain the Gas Laws: Pressure-Volume Relationship (Boyle?s Law) P? 1/V or V ? 1/P (at constant n, T) Pressure-Temperature Relationship (Guy-Lussac?s Law) ?T, ?v ?v, ?P Volume-Temperature Relationship (Charles?s Law)

Bob Jones PPT Notes -- Chapter 10c

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Gases and the Mole Gay-Lussac formulated the law of combining volumes. Law of Combining Volumes Gases at the same temperature and pressure react with one another in volume ratios of small whole numbers. Law of Combining Volumes Example 1: H2 + Cl2 2HCl 1 L + 1 L 2 L Law of Combining Volumes Example 2: 2H2 + O2 2H2O 2 L + 1 L 2 L Avogadro?s law The volume of a gas, maintained at a constant temperature and pressure, is directly proportional to the number of moles of the gas. Molar Volume the volume that a mole of gas occupies at standard temperature and pressure Molar Volume 1 mole of ANY gas at STP occupies 22.4 L. Sample Problem 1 What volume would 7 moles of carbon dioxide occupy at STP? = 157 L CO2 7 mol CO2 22.4 L 1 mol Change 228 L of O2 at STP to moles. 470 moles 426 moles

Bob Jones PPT Notes -- Chapter 10b

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Gas Laws Standard Temperature and Pressure (STP) Standard temperature: 0?C or 273 K Standard pressure:1 atm, 760 mm Hg, or 101.3 kPa Boyle?s Law The pressure of a dry gas is inversely proportional to its volume if the temperature is held constant. Inverse Proportion two terms related so that, if one term increases, the other term decreases Boyle?s Law P V , PV = k P1V1 = P2V2 As pressure increases, volume decreases. 6 Chemistry textbook, p. 250 7 Chemistry textbook, p. 250 P1V1 = P2V2 Sample Problem 1 A sample of gas occupies 352 mL at a pressure of 3.17 atm. If the P is reduced to 1.24 atm, what volume will result? (3.17 atm)(352 mL) = (1.24 atm)V2 900 mL = V2 A sample of gas occupies 200 mL at a P of 2.15 atm. If the P is reduced to 1.25 atm, what is V2? 344 mL 537 mL 98 mL 89 mL

Gas laws

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A Gas Uniformly fills any container. Mixes completely with any other gas Exerts pressure on its surroundings. A Gas It might help to define a gas based on the other phases as well. -Movie Clip- Kinetic Molecular Theory 1. Volume of individual particles is ? zero. 2. Collisions of particles with container walls cause pressure exerted by gas. 3. Particles exert no forces on each other. 4. Average kinetic energy ? Kelvin temperature of a gas. The Meaning of Temperature Kelvin temperature is an index of the random motions of gas particles (higher T means greater motion.) -Kinetic Energy Video- Pressure is equal to force/unit area SI units = Newton/meter2 = 1 Pascal (Pa) 1 standard atmosphere = 101,325 Pa 1 standard atmosphere = 1 atm = 760 mm Hg = 760 torr atm mmHg torr
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