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Electrophile

Organic Chapter 11 ppt

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Chapter 11 Reactions of Alcohols Organic Chemistry, 6th Edition L. G. Wade, Jr. Chapter 11 * Types of Alcohol Reactions Dehydration to alkene Oxidation to aldehyde, ketone, acids Substitution to form alkyl halide Reduction to alkane Esterification Tosylation Williamson synthesis of ether => Chapter 11 Chapter 11 * Summary Table => Chapter 11 Chapter 11 * Oxidation States Easy for inorganic salts CrO42- reduced to Cr2O3 KMnO4 reduced to MnO2 Oxidation: loss of H2, gain of O, O2, or X2 Reduction: gain of H2 or H-, loss of O, O2, or X2 Neither: gain or loss of H+, H2O, HX => Chapter 11 Chapter 11 * 1?, 2?, 3? Carbons => Chapter 11 Chapter 11 * Sample Problems (1)

Organic Chapter 6 ppt

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Chapter 6 Alkyl Halides: Nucleophilic Substitution and Elimination Organic Chemistry, 6h Edition L. G. Wade, Jr. Chapter 6 * Classes of Halides Alkyl: Halogen, X, is directly bonded to sp3 carbon. Most reactions result from breaking of this bond. C ? X bond is polar (EN difference) C is slightly positive ? electrophilic (can be attacked by nucleophile) X can leave with electrons ? elimination X can be replaced with another functional group ? substitution Chapter 6 Chapter 6 * Classes of Halides Examples: CHCl3 ? chloroform (solvent) CHClF2 ? freon-22 (refrigerant) CCl3 ? CH3 ? 1,1,1-trichloroethane (cleaning fluid) CF3 ? CHClBr ? halothane (nonflammable anesthetic) Chapter 6 Chapter 6 * Classes of Halides Vinyl: X is bonded to sp2 carbon of alkene. Examples:

Organic Chapter 4 ppt

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Chapter 4 The Study of Chemical Reactions Organic Chemistry, 6th Edition L. G. Wade, Jr. Chapter 4 * Introduction Reactants ? Products: overall reaction. Mechanism: complete step-by-step description of exactly which bonds break and form in what order to give observed products To learn more about a reaction: Thermodynamics Kinetics. => Chapter 4 Chapter 4 * Thermodynamics study of energy changes provides an opportunity to: compare stability of reactants and products predict which compounds are favored Kinetics study of reaction rates, determining which products form the fastest helps predict how the rate will change if conditions are changed Chapter 4 Chapter 4 * Chlorination of Methane

Psyc Ch. 6

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Alkenes are commonly described as unsaturated hydrocarbons because they have the capacity to react with substances that add to them. Alkanes, on the other hand, are saturated hydrocarbons and are incapable of undergoing addition reactions. 6.1 Hydrogenation of Alkenes The relationship between reactants and products in addition reactions can be illustrated by the hydrogenation of alkenes to yield alkanes. Hydrogenation is the addition of H 2 to a multiple bond, as illustrated in the conversion of ethylene to ethane. The reaction is exothermic and is characterized by a negative sign for ?H?. Indeed, hydrogenation of all alkenes is exothermic. The heat given off is called the heat of hydrogenation and cited without a sign. In other words, heat of hydrogenation = -?H?.
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