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Question involving calorimetry

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Panman's picture
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Joined: Jan 2006
Question involving calorimetry

Hey i need help with this 1 question. I've looked through my AP Chem book but it does not really help much with this type of problem:

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Juan performed a calorimetry experiment to determine ∆H for the following reaction: KOH (s) --> K(aq) + OH(aq)

His calorimeter contained 64.0 g of water at an initial temperature of 20.7°C. When he added 1.65 g of KOH (s) to the calorimeter, the temperature rose to 26.9°C. What value of ∆H can Juan obtain fromhis data?
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I really dont know where to start and the only formula i know for this type of problem is q=ms∆t but that does not really help finding ∆H. The only ∆H problem i have worked with are ones concerning Hess's Law.

Thanks in advanced.

xenahorse's picture
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Joined: Sep 2005

Your problem is that you're getting confused by all the diffrent symbols used to represent stuff in Chem. What does ∆H stand for? The change in enthalpy, or the change in heat. Now, what does q (from the equation you said you've used, q=ms∆t) stand for? Heat, specifically the change in heat occuring because of a change in mass or temperature. So the ∆H you need to find is the same as q. All you really have to do is plug the data into the equation q=ms∆t and chug out an answer! Have fun....


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chessmaster1990's picture
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Joined: Oct 2005

I disagree!

you can find the energy
Q=mcat
Q = 64 * 4.18 * 5.8 = 1552

If all they were looking for was the Q then they would have not given you the mass of KOH

when you add 1.65 g of KOH, that means you are adding 1.65/(39 + 16 + 1) = 0.0295 moles. So...if 0.0295 moles produces 1552 Joules of energy, that means that the delta H of dissociation for KOH = 1552/0.0295 = 52.7 kJ/mol

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you think studying is fun.
you constantly find yourself saying "we had homework?"
everything you know about sex, you learned in english class.

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xenahorse's picture
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Joined: Sep 2005

Oops. I guess I shoulda read the question more clearly. Thanks forcatching that, chessmaster. Sorry 'bout that, Panman. That teaches me a lesson...


The hardest thing about riding horses is the ground
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[=1]Made by moi^:D[/

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